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TOS 39 through 48 are from Marvel's Comic Book Library Vol. 1 - CD ROM, 51 - 58 are from Marvel Masterworks, Vol. 45. 59-68 are from the CD-ROM (Cap. America's 1st ten issues). The rest of the Iron Man covers are from my own individual issues or Iron Man: The Complete Collection of comics on DVD up through 2000 or from where I can find a copy. 
The Avenger first ten issues are from the CD-ROM as well.
During Vol 4, the Inevitable came out in 2006. After Iron Man Vol 4, then The Invincible Iron Man Vol 1 was next, then Iron Man Vol 5
The
Iron Man Timeline: List of Milestones
Iron Man Vol 6Iron Man Vol 6
Iron Man Vol 6Iron Man Vol 6Iron Man Vol 6
Iron Man Vol 6Iron Man Vol 6Iron Man Vol 6Iron Man Vol 6
Iron Man Vol 6Iron Man Vol 6Iron Man Vol 6
Iron Man Vol 6Iron Man Vol 6
Iron Man Vol 6
Iron Man Vol 6Iron Man Vol 6
The Invincible Iron Man Vol 2The Invincible Iron Man Vol 2
The Invincible Iron Man Vol 2The Invincible Iron Man Vol 2The Invincible Iron Man Vol 2
The Invincible Iron Man Vol 2The Invincible Iron Man Vol 2The Invincible Iron Man Vol 2The Invincible Iron Man Vol 2
The Invincible Iron Man Vol 2The Invincible Iron Man Vol 2The Invincible Iron Man Vol 2
The Invincible Iron Man Vol 2The Invincible Iron Man Vol 2
The Invincible Iron Man Vol 2
The Invincible Iron Man Vol 2The Invincible Iron Man Vol 2
I AM IRON MANI AM IRON MAN
I AM IRON MANI AM IRON MANI AM IRON MAN
I AM IRON MANI AM IRON MANI AM IRON MANI AM IRON MAN
I AM IRON MANI AM IRON MANI AM IRON MAN
I AM IRON MANI AM IRON MAN
I AM IRON MAN
I AM IRON MANI AM IRON MAN
I AM IRON MAN
Invincible Iron Man V2
I AM IRON MAN
Iron Man The Inevitable
Age of InnocenceAge of Innocence
Age of InnocenceAge of InnocenceAge of Innocence
Age of InnocenceAge of InnocenceAge of InnocenceAge of Innocence
Age of InnocenceAge of InnocenceAge of Innocence
Age of InnocenceAge of Innocence
Age of Innocence
Age of InnocenceAge of Innocence